PPLN Λ = 18.99 µm · 1550 → 775 nm · 2 px/µm

2.3 Second-order nonlinear optics

L1 Phenomenon

SHG 1550 → 775 nm, bulk CLN and TFLN

The polarization of LN contains a term quadratic in the optical field (χ(2)), so two photons merge into one at the sum frequency (SFG; SHG when both are equal) or one photon splits into two (DFG; parametric amplification). The largest coefficient, d33, couples fields all polarized along c.

Dispersion makes 775 nm light slower than 1550 nm light in bulk CLN: the second harmonic slips out of phase after the coherence length Lc = π/Δk = 9.495 µm derived and converts back. Reversing the ferroelectric domain every Lc (period Λ = 18.99 µm, PPLN) restarts the growth in every domain, and the harmonic power grows as L2. In a TFLN waveguide etched from a sub-micrometre film the period is near 4 µm, set by waveguide dispersion reported; measured normalized efficiencies reach thousands of percent per watt per square centimetre (L2).

SHG along z, 1550 → 775 nm, e + e → eRK4 · eq. 2.13 · tanh²
d(z) |±±±±±±±±±±±±±±±±±±±±±±±±±±±±±±±±±±±±±±±±±±±±±±±±±±±±±±±±±±±±|
     0                                              z = L = 10.0 mm
02468100.00.51.01.52.0z (mm)P2ω (mW)
RK4, coupled-mode equationsundepleted, eq. 2.13P0 tanh², QPM
Poling
Unpoled Δk
ηnorm, %/W/cm²
10.0 mW
 10.0 mm
0.50
0.00 dB/cm
P axis
P2ω(L), RK42.208e−03 Wderived
P2ω(L) / Pω(0)2.208e+01 %derived
eq. 2.13, undepleted2.600e−03 Wderived
Pω(L) / Pω(0) 77.922 %derived
ηnorm (input)2600 %/W/cm²reported
ηnorm sin²(πD) L², QPM   2600.0 %/Wderived
Lc = Λ/2 (unpoled)  9.495 µmderived
|Pω + P2ω − P0| / P0, lossless9.5e−15derived
ηnorm: measured values (L2 table) reported; loss and D are inputs template. QPM: domain-averaged coupling. Unpoled: full d33 with the bulk or TFLN mismatch; the harmonic oscillates with period 2Lc. Strip: 1 character = L/60; ± = domains finer than one character.
from z = 0 at 2 px per µmΛ = 18.989 µm, D = 0.50
50 µm
0L = 10.0 mm527 periods, finer than the drawing02468100.00.51.01.52.0z (mm)P2ω (mW)

Drawntop: the guide from z = 0 at 2 px per µm (at most the first 450 µm); middle: the whole guide, 775 nm glow scaled to its maximum in each view; dashed: 1550 nm pump, width = remaining power. Poling off: the glow pulses every coherence length. Periodic poling: it grows monotonically; at watts the curve bends from L² to tanh² as the pump thins. Curves: RK4 of the coupled-mode equations (solid), undepleted eq. 2.13 (dashed), P0 tanh² (dotted, QPM). QPM uses the domain-averaged coupling κ² = ηnorm sin²(πD); without poling the full d33 acts with the bulk or TFLN mismatch. Loss and duty cycle are inputs template.

ηnorm measured reported curves: coupled-mode RK4, eq. 2.13, tanh² derived pump 1550 nm: false color, dashed; SH 775 nm: deep red
Poling
Mismatch without poling
Measured ηnorm, %/W/cm²
Power axis
10.0 mW
 10.0 mm
0.50
0.00 dB/cm
Second harmonic at L, RK4
2.208e−03 W
Converted P2ω/Pω(0)
2.208e+01 %
Undepleted, eq. 2.13
2.600e−03 W
Pump remaining
 77.922 %
Measured ηnorm (input)
2600 %/W/cm² reported
Low-power efficiency, QPM
   2600.0 %/W
Coherence length Lc (unpoled)
  9.495 µm
Energy check, lossless
9.5e−15

L2 Quantitative model

3m d tensor, eq. 2.10 to 2.13

d tensor

Contracted index l: 1 = xx, 2 = yy, 3 = zz, 4 = yz, 5 = xz, 6 = xy. Point group 3m with Kleinman symmetry (d15 = d24 = d31; Kleinman 1962):

d=(0000d31−d22 −d22d220d3100 d31d31d33000)(2.10)
Pi(2ω)=2ε0∑ldil(Ex2,Ey2,Ez2,2EyEz,2ExEz,2ExEy)l(2.11)

Complex-amplitude convention of Boyd 2008; χ(2) = 2d. For two distinct input frequencies (SFG) the prefactor is 4ε0.

Values (pm/V)

No source held tabulates a post-1997 absolute d set: every value below is a legacy-scale compilation, a secondary table without per-cell references, or unverified. No set is used as default.

SourceFundamentald33d31d22ScaleStatus
Volk & Wohlecke Table 1.2 (CLN), citing Nikogosyan 20051.06 µm3463legacyP-comp
same, near-SLN1.06 µm4252.5legacyP-comp
Zhu et al. review Table 1 (no per-cell reference)1064 nm−27.0−4.32.10not statedS
Shoji et al. 1997, absolute scale1.064 µm25.2 claimedabout 4.6 claimed–post-1997U
Kitamoto et al. 1995, parametric fluorescence488 / 532 nm pump–4.8 ± 0.5 / 4.3 ± 0.5 claimed–post-1997 methodU

Weis & Gaylord 1985 has no SHG d table. The legacy d33 = 34 pm/V is 35% above the claimed 25.2 pm/V U, which attributes the older values to multiple-reflection errors (claim, abstract only). Miller's rule scales χ(2) with the product of the linear susceptibilities at the three frequencies; Shoji et al. report that it holds poorly for LN (claim) U.

Field mapping (eq. 2.10, no further assumption)

Cut, modeFieldsActive coefficientPhase matching
x-cut, TE, propagation yE along z at ω and 2ωd33QPM, type 0 (e + e → e)
z-cut, TME mostly along zd33QPM, type 0
z-cut, TE, in-plane field at α from xE in xyTE SH: −2ε0d22E² sin 3α, largest for E along y (propagation x), zero for E along x (propagation y); TM SH via d31modal or QPM
bulk, type I (o + o → e)ordinary inputs, no z componentd31, d22 onlybirefringent, angle-tuned

Birefringent phase matching never uses d33: ordinary inputs have no z component, so only the xx, yy, xy columns act.

d tensor: which coefficient a cut and polarization usessymbolic
Cut
Input field
  0°
Coefficient set
P/(2ε0E²)× d33× d31× d22pm/V
x 0.000 0.000 0.000      –
y 0.000 0.000 0.000      –
z+1.000 0.000 0.000      –
onto TE out+1.000 0.000 0.000      –
onto TM out 0.000 0.000 0.000      –
1 xx2 yy3 zz4 yz5 xz6 xy
x0000d31−d22
y−d22d220d3100
zd31d31d33000
            z               
            |               
            |               o: E along x (TM)
            |               +: origin
············+----------ky   k at   0° from y
            |               
            |               
            |               
x-cut, normal x             
k ( 0.00, +1.00,  0.00)E ( 0.00,  0.00, +1.00)active: d33        
Propagation angle from the first in-plane axis (x-cut: y; y-cut and z-cut: x) toward the second. TE: in-plane field perpendicular to k; TM: field along the wafer normal. z-cut TE puts E in the xy plane, the field of an ordinary wave in bulk. Inverted cells: coefficients the input drives. Rotating z-cut TE through 180° never drives d33, and the TE response repeats every 120°. Numbers: 1.06 µm values of the selected set.
xyc (z)kE 1550 nmd33xxyyzzyzxzxyxd31−d22y−d22d22d31zd31d31d33dil, Kleinman: d15 = d24 = d31; filled: driven by this input

z-cut TE puts E in the xy plane, the field of an ordinary wave in bulk: rotating it through 180° never drives d33, only d31 and d22, and the TE response repeats every 120°. x-cut TE is driven by d33 alone. Propagation angle from the first in-plane axis (x-cut: y; y-cut and z-cut: x) toward the second; TE: in-plane field perpendicular to k; TM: field along the wafer normal. Numbers: 1.06 µm values of the selected set.

input 1550 nm: false color, dashed, double arrow = oscillating field radiated P(2ω), 775 nm: deep red, drawn downstream along k; with symbols, one arrow per coefficient
Crystal cut
Input field
  0°
Coefficients symbolic
Propagation k
( 0.00, +1.00,  0.00)
Field E
( 0.00,  0.00, +1.00)
P/(2ε0E²)
d33 ( 0.00,  0.00, +1.00)
SH field along TE
d33
SH field along TM
0
Coefficients driven
d33

Phase matching

Wave-vector mismatch with an m-th order grating of period Λ (phase matching at Δk = 0):

Δk=k3−k1−k2−2πmΛ(2.12)

Birefringent, type I SHG, bulk CLN, 21 °C. 1550 nm: θpm = 49.55° from c, SH walk-off 2.034° derived; 2000 nm: 45.01° derived. 1064 nm: no angle exists, since ne(532 nm) − no(1064 nm) = +1.46×10−3 > 0 derived; 1064 nm type-I SHG in CLN needs temperature tuning (noncritical phase matching).

Quasi-phase matching. Order m, duty cycle D (Fourier coefficient of the square-wave sign of d; form as in Fejer et al. 1992), so (2/π) d33 at D = 0.5, m = 1:

deff=2mπd33sin(mπD)
Process, bulk CLN, e + e → e, 21 °CΛ (µm)Lc = Λ/2 (µm)Status
SHG 1064 → 532 nm6.8183.409derived
SHG 1550 → 775 nm (also degenerate OPO pumped at 775 nm)18.9899.495derived
SHG 2090 → 1045 nm31.0715.54derived
DFG / OPO: pump 1064, signal 1550, idler 3393.4 nm29.9114.96derived

Jundt ne at 24.5 °C gives 18.976 µm for 1550 nm SHG derived. TFLN waveguides shift the period to a few µm because neff disperses differently from bulk ne; x-cut films have been poled at 600 nm reported and 747 nm periods reported. Early thin-film PPLN converters: Chang et al. 2016.

Undepleted and depleted SHG

P2ω=ηnormPω2L2sinc2(ΔkL2),ηnorm=8π2deff2ε0cnω2n2ωλω2Aeff(2.13)

ηnorm computed from d33 inherits the d spread. Eq. 2.13 at 1550 nm with bulk indices, Aeff = 1 µm² template, deff = (2/π) d33:

d33 sourced33 (pm/V)deff (pm/V)ηnorm (%/W/cm²)Status
Volk & Wohlecke, CLN, legacy scale P-comp34.021.65828derived
same, near-SLN P-comp42.026.78893derived
Zhu et al. review, |d33| S27.017.23675derived
Shoji et al. 1997, claimed U25.2 claimed16.03201 claimedU

Depleted, at Δk = 0 (Armstrong et al. 1962):

P2ω=P0tanh2(ηnormP0L)

Bulk focusing cannot reach the L2 law: a Gaussian beam diffracts, the optimum confocal parameter is b = L/2.84 reported, and P2ω then grows only linearly in L. Waveguides hold Aeff fixed over centimetres, hence the L2 law and the 1/Aeff gain.

Measured normalized efficiencies

Sort
DeviceValueNormalizationDateStatus
LiNbO3 waveguide, field-poled at room temperature, first-order QPM, blue SHG600 %/W/cm²; 20.7 mW bluewaveguide1993-02-01reported
TFLN PPLN, 1.5 µm pump, 4 µm period2600 %/W/cm²waveguide2018-11-07reported
TFLN, shallow etch, MgO, 5 mm3757 %/W/cm² (939 %/W)waveguide2020-06-19reported
TFLN, actively monitored poling4600 %/W/cm²waveguide2019-08-28reported
double-layer, polarization-reversed TFLN9600 %/W/cm² measured; >10,000 theory; 85% absolute at high powerwaveguide2024-11-07reported
TFLN, blue SHG33,000 %/W/cm²waveguide2022-05-19reported
TFLN on sapphire, DFG to 3.66 µmup to 200 %/W/cm²waveguide (DFG)2021-06-16reported
TFLN, modal phase matching (no poling), 8 mm4.7 %/Wwaveguide, %/W2018-08-16reported
z-cut PPLN microring250,000 %/Wring2019-11-21reported
PPLN microring; g/2π about 1.2 MHz5,000,000 %/Wring2020-11-23reported

Waveguides: %/W/cm² = P2ω/(Pω²L²); rings: %/W. The two units are not convertible without a model (L3). Dates: issue dates.

Acceptance bandwidths

sinc²(x/2) falls to one half at x = ±2.783, so the full width at half maximum in any parameter q is

δq=2×2.783L|∂Δk/∂q|=5.566L|∂Δk/∂q|
SHG pump, bulk CLN, first-order QPMFWHM in λω × L, Zelmon 21 °C (nm cm)FWHM in T × L, Jundt 25 °C (K cm)dλω/dT, Jundt 25 °C (nm/K)
1064 nm0.205 derived3.21 derived0.064 derived
1550 nm1.176 derived10.12 derived0.115 derived

Thermal expansion of the period not included. The temperature acceptance shifts with the reference temperature: 1550 nm SHG 10.14 K cm at 24.5 °C, 10.26 K cm at 21 °C derived.

Group-velocity mismatch, bulk, e-polarized 1550/775 nm: Δng = 0.0905, 302 fs/mm derived. Comparison with a TFLN device: Zhao et al. report a 1 nm linewidth for 5 mm and 0.1 nm/°C tuning reported; bulk CLN scaled to 5 mm gives 2.35 nm derived and 0.115 nm/K derived. Waveguide dispersion lets nanophotonic PPLN cancel group-velocity mismatch and run femtosecond SHG with < 100 fJ reported.

Phase matching, bulk CLN, eq. 2.12e + e → e QPM; o + o → e BPM
Pump (SHG)
Process
1.550 µm
1.064 µm
QPM order m
0.50
 10.0 mm
 40.0 °C
   0.0 nm
ne for Λ
λSH0.775 µmderived
Λ, order m = 1  18.989 µmderived
Lc = π/Δk   9.495 µmderived
deff/d33 = 2 sin(mπD)/(mπ)  0.6366   derived
θpm type I (o + o → e) 49.55°derived
walk-off ρ of the e wave 2.034°derived
FWHM in λω at L (SHG)   1.176 nmderived
FWHM in T at L (SHG, Jundt)    9.64 K derived
dλω/dT at fixed Λ (SHG, Jundt)  0.1205 nm/Kderived
GVM 1/vg,2ω − 1/vg,ω (SHG)   301.9 fs/mmderived
grating Λg = mΛ(40 °C) + ΔΛ (SHG, Jundt) 18.9264 µmderived
Δk at λω, T, Λg (eq. 2.12)   0.000 rad/mmderived
ΔkL/2   0.000 radderived
sinc²(ΔkL/2)  1.0000   derived
SH power / matched 1st order, D = 0.5  1.0000   derived
FWHM in Λ at L   31.73 nmderived
Curve versus
30354045500.00.51.0T (°C), Jundtsinc²(ΔkL/2)
bulk CLN, order 1, Λ 18.989 µm, D 0.50
|+++++++++----------+++++++++----------+++++++++---|
TFLN, Λ 4 µm reported (Wang et al. 2018, 1.5 µm pump)
|++--++--++--++--++--++--++--++--++--++--++--++--++|
 0         10        20        30        40        50 µm
SH 775 nm |########################################| 1.000
λ1: fundamental (SHG), first input (SFG), pump (DFG); λ2: second input (SFG), signal (DFG, idler from energy conservation). Fixed grating Λg = mΛ1(λω, 40 °C, Jundt) + ΔΛ, operated at T: the curve shows sinc²(ΔkL/2) of that grating versus the selected parameter, band = FWHM, marker = operating point; the bar shows the generated SH power relative to a matched first-order grating with D = 0.5 derived. Jundt ne is defined from 20 to 250 °C, so a curve ends where T leaves that window. Period expansion with T not included. BPM angle: Zelmon 21 °C. TFLN strip: reported period reported.
Bulk CLN, order 1, computedΛ = 18.989 µm = 38.0 px
TFLN waveguide, reportedΛ ≈ 4 µm at 1.5 µm pump = 8 px
50 µm at 2 px per µm
pump 1550 nmL = 10.0 mm, Λg = 18.926 µm, T = 40.0 °CSH 775 nm, sinc² 1.00030354045500.00.51.0T (°C), Jundtsinc²(ΔkL/2)

Drawndomains at 2 px per µm: the computed bulk period (1550 nm SHG: 38 px) above the reported TFLN period (8 px). Below, a fixed grating Λg = mΛ1(40 °C, Jundt) + ΔΛ: the generated beam, in the color of its wavelength, is as bright as sinc²(ΔkL/2) allows; heat the crystal or offset the period and it fades, then flickers through the side lobes. The curve shows the same sinc² versus the selected parameter, area inside the FWHM filled, diamond = operating point. First wavelength: fundamental (SHG), first input (SFG) or pump (DFG); second: second input (SFG) or signal (DFG, idler from energy conservation). Curve and beam: Jundt ne, defined from 20 to 250 °C, so a curve ends where T leaves that window; brightness relative to a matched first-order grating with D = 0.5. Period expansion with T not included. Type-I angle: Zelmon 21 °C.

periods, angles, bandwidths derived temperature values: Jundt derived detuned beam and curve derived TFLN period reported IR: false color, dashed
Pump, SHG
Process
1.550 µm
1.064 µm
QPM order
0.50
 10.0 mm
 40.0 °C
   0.0 nm
Index model for the period
Curve versus
Output wavelength
0.775 µm
Period Λ, order 1
  18.989 µm
Coherence length
   9.495 µm
deff / d33
  0.6366
Type-I angle from c
 49.55°
FWHM in wavelength
   1.176 nm
FWHM in temperature
    9.64 K
Tuning dλ/dT
  0.1205 nm/K
Group-velocity mismatch
   301.9 fs/mm
Grating Λg
 18.9264 µm
Δk
   0.000 rad/mm
ΔkL/2
   0.000 rad
sinc²(ΔkL/2)
  1.0000
SH power / matched 1st order
  1.0000
FWHM in Λ
   31.73 nm

L3 Normalizations and conventions

%/W/cm², %/W, absolute %, pulse energy

Why the efficiency numbers do not compare directly

NormalizationDefinitionValid whenBreaks when
%/W/cm² (ηnorm)P2ω/(Pω²L²), low-power slope, phase matcheduniform QPM, no loss, undepleted; on-chip powersnonuniform film or poling (effective length < L, so ηnorm falls with L); loss; quoted with fiber-coupled powers
%/WP2ω/Pω² for one devicerings and resonators; also whole waveguidescompares devices of different length or Q; a ring value scales with resonant build-up
absolute %P2ω/Pω at a stated pumphigh-power, depleted regimesays nothing about low-power efficiency
pulse energy (fJ, pJ)energy at which a stated conversion or gain is reachedfemtosecond, dispersion-engineered devicesnot convertible to CW numbers without the pulse shape

Ring build-up from coupled-mode theory, H/ħ = g(a²b† + h.c.), energy decay rates κa (fundamental), κb (SH), external rates κa,ex, κb,ex, zero detuning derived:

PbPa2=64g2κa,ex2κb,exωbħωa2κa4κb2→κex=κ/216g2ħωaκa2κb

At fixed g a ring's %/W therefore scales as Q3. Published definitions of g differ by numerical factors, so g values from different papers are compared only after conversion to one Hamiltonian. ηnorm scales as 1/(λ²Aeff) at fixed deff (eq. 2.13); Aeff itself scales roughly with λ² in a geometrically scaled guide, and deff disperses (Miller). Blue SHG at 33,000 %/W/cm² reported and 1550 nm SHG at 2600 to 9600 %/W/cm² are therefore not ranked by one number.

Overlap

For dominant field components normalized to unit power, the integral in the numerator runs where d is nonzero (LN, with sign flips in poled regions). Some authors fold neff into this definition.

1Aeff=|∫χ(2)E2ω*Eω2dA|2(∫|Eω|2dA)2∫|E2ω|2dA

Coupled-mode equations

|A|² = power, fields written as A exp(i(ωt − kz)), the complex conjugate of the convention in Boyd, so phases of A carry the opposite sign (Armstrong et al. 1962). The equations conserve Pω + P2ω (Manley-Rowe) and reproduce eq. 2.13 and the tanh² law; the SHG figure in L1 integrates them by RK4.

dAωdz=−iκA2ωAω*e−iΔkz,dA2ωdz=−iκAω2eiΔkz,κ2=ηnorm

Error sources in measured ηnorm

Facet-loss calibration at two wavelengths (the SH often exits multimode); poling duty-cycle errors and missing domains (deff falls as sin πD; Fejer et al. 1992); film-thickness variation that moves the phase-matching wavelength along the device, which adapted poling compensates (Chen et al. 2024); photorefraction and green-induced infrared absorption at high SH power (chapter 04). The d scale carries the largest systematic uncertainty: 25 vs 34 pm/V changes ηnorm by 1.85× derived.

Reviews: TFLN platform (Zhu et al. 2021); LN photonics from UV to microwave (Boes et al. 2023); LNOI phase-matching schemes (BPM, modal, QPM) and tuning effects (You et al. 2024).

Reported SHG efficiencies by dateone unit per panel
1001000104105%/W/cm² (normalized: P2ω/(Pω²L²))199019952000200520102015202020251100104106108%/W (P2ω/Pω², one device)η inputηL²ring Q³Yamada et al. 1993Wang et al. 2018Rao et al. 2019Zhao et al. 2020Mishra et al. 2021Park et al. 2022Li et al. 2024Luo et al. 2018Zhao et al. 2020Lu et al. 2019Lu et al. 2020
2018-11-07Wang et al. 20182600 %/W/cm²waveguide, normalizedreportedTFLN PPLN, 1.5 µm pump, 4 µm period
■ waveguide %/W/cm²□ DFG %/W/cm²▲ waveguide %/W◆ ring %/Wconverterring model
Show
y axes
 2600 %/W/cm²
 5.00 mm
1.00e+05
1.00 MHz
ηnorm L² at the set L     650.0 %/Wderived
ring, critical coupling, Qa = Qb = Q1.373e+05 %/Wderived
κa/2π = νa/Q (1550 nm)    1934.1 MHzderived
Hover a marker for its record. Values: the L2 table, each as reported. Ring model: 1550 nm fundamental, critical coupling. The Q slider moves only the lower panel.
1001000104105%/W/cm² (normalized: P2ω/(Pω²L²))199019952000200520102015202020251100104106108%/W (P2ω/Pω², one device)η inputηL²ring Q³1993 field-poled LN waveguideYamada et al. 1993Wang et al. 2018Rao et al. 2019Zhao et al. 2020Mishra et al. 2021Park et al. 2022Li et al. 2024Luo et al. 2018Zhao et al. 2020Lu et al. 2019Lu et al. 2020

TFLN PPLN, 1.5 µm pump, 4 µm period reported

Drawnupper panel per watt and square centimetre, lower panel per watt for one device; a point never appears on a panel of another unit. Drag Q: the ring line climbs as Q³ past the ring records while the upper panel stays still. Marker fill: color of the generated light where the source gives the pump wavelength; IR output dashed. Values: the measured-efficiency table in L2, each as reported. Ring model: 1550 nm fundamental, critical coupling, Qa = Qb = Q; g/2π is a display parameter template.

records as reported reported converter and ring model derived gold rule: the 1993 field-poled waveguide reported
Show
Vertical scale
 2600 %/W/cm²
 5.00 mm
1.00e+05
1.00 MHz
Record
Wang et al. 2018
Issue date
2018-11-07
Value
2600 %/W/cm²
Normalization
waveguide, normalized
ηnorm L² at the set L
     650.0 %/W
Ring model %/W (critical, Qa = Qb)
1.373e+05
κa/2π = νa/Q (1550 nm)
    1934.1 MHz

References

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